C-H bond activation using palladium catalysts, iridium catalysts, and iron catalysts
Keywords:
Carbon-Hydrogen bond activation, cross coupling, Carbon-carbon bond, synthetic methods, organic chemistryAbstract
Recently, there have been a large number of reports on “C-H bond activation reaction”. C-H bond activation is a methodology for directly forming carbon-carbon bonds by activating a carbon hydrogen bond, which is the most fundamental linkage in organic chemistry. Traditional cross coupling reactions have been one of the most useful synthetic methods for the formation of carbon carbon bonds. However, the cross coupling reaction requires extra procedures for preparing organic halides (or triflates) compounds, and organic boron or metal compounds.On the other hand, the C-H bond activation can reduce these procedures, thus making this reaction a cost-effective and ecofriendly system.
References
S. Murai, F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani,
Nature 1993, 366, 529.
K. L. Hull, M. S. Sanford, J. Am. Chem. Soc. 2007, 129, 11904.
M. S. Chen, N. Prabagaran, N. A. Labenz, M. C. White, J. Am. Chem. Soc. 2005,
127, 6970.
K. J. Fraunhoffer, N. Prabagaran, L. E. Sirois, M. C. White, J. Am. Chem. Soc.
2006, 128, 9032.
T. Ishiyama, J. Takagi, K. Ishida, N. Miyaura, N. R. Anastasi, J. F. Hartwig, J. Am.
Chem. Soc. 2002, 124, 390.
J. Emsley, in The Elements, 3rd ed., Oxford Univ. Press, New York, 1998.
T. Nagano, T. Hayashi, Org. Lett. 2004, 6, 1297; K. G. Dongo, H. Koh, M. Sau, C.
L. L. Chai, Adv. Synth. Catal. 2007, 349, 1015; T. Hatakeyama, M. Nakamura, J.
Am. Chem. Soc. 2007, 129, 9844.
F. Vallee, J. J. Mousseau, A. B. Charette, J. Am. Chem. Soc. 2010, 132, 1514.
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors contributing to this journal agree to publish their articles under the Creative Commons Attribution 4.0 International License, allowing third parties to share their work (copy, distribute, transmit) and to adapt it, under the condition that the authors are given credit and that in the event of reuse or distribution, the terms of this license are made clear.
