Preparation of Neem Oil and Acrylonitrile Based Copolymeric Materials as a Potential Bio-Based Additives and Its Effect on Pour Point Depressant of a Lube Oil

Authors

  • Faisal Sanusi Dept. of pure and applied chemistry, Umaru Musa Yar’adua University, Katsina, Nigeria
  • Aminu Musa Dept. of pure and applied chemistry, Umaru Musa Yar’adua University, Katsina, Nigeria
  • Auwal Bello Dept. of pure and applied chemistry, Umaru Musa Yar’adua University, Katsina, Nigeria

Keywords:

Neem oil, Antioxidant, Copolymeric materials, lube oil, pour point depressant, Biodegradability (green additives)

Abstract

In other to minimize environmental pollution, green additives prepared from bio-source with low cost and multi-functional applications have driven considerable attention in the field of lube oil industry. In this research, Neem oil was extracted using n-hexane as a solvent and some amount of Neem oil has mixed with turmeric rhizome (Antioxidant) to ascertain its oxidative stability and it was examined by FT-IR analysis. Copolymer derived from Neem oil and acrylonitrile was prepared by direct polymerization through the double bond of the fatty acid chain in the present of free radical initiator led to the formation of environmentally friendly Copolymeric based additives. The prepared Copolymer have been characterized by routine spectroscopic analysis. The rheological behavior and performance evaluation of the lube oil were examined in different concentration of additive Viz. 1% 2% 3% (w/v). However, the green additive act as good pour points depressant improver to the lube oil. The values of pour point for the lube oil blended with different prepared Copolymeric additives ranging from (9 to -110C). Thus, bio-based oil derived additive can be considered as a good alternative to be used in lube oil formulation.

 

References

Mohammed, A., Dhedan, R. M., Mahmood, W. A., & Musa, A."Copolymers of Castor and Corn Oils with Lauryl Methacrylate as Green Lubricating Additives. Egyptian Journal of Chemistry, 64(8) pp. 4271-4276, 2021.

Kumar, D., S. “Modification of lube oil properties by addition of organic polymeric additives”. North Bengal university, India- 3(6) pp. 734013, 2018

Musak, Y., Kovalenko, T., Serdiuk, V., Kravets, T., &Martynyak-Andrushko, M. “Obtaining of polymethacrylate additives and study in operational properties of an alloyed industrial Oil”. Eastern-European Journal of Enterprise Tecnologies, pp. 9-15, 2016.

Saha, D.K., &Ghosh,P. “Synthesis, characterization and performance evaluation of Long chain methacrylate-octene copolymer for Lubricant formulation”. Journal Macromolecular Science, Part A, 56(11) pp. 1050-1059, 2019.

Karmakar. G., Dey, K., Ghosh, P., Sharma, B.K., &Erhan,S Z. “A short review on polymeric biomaterials as additives for lubricants”. Polymers, pp. 1333, 2021.

Agarwal, p., S., Portal, J., Singh, R. K., &Portal, S. K. “Evaluation of renewable feedstock-derived Copolymer of stearyl methacrylate-co-triglyceride as multifunctional green additives in lubricant”. Polymer Bulletin, pp. 1-16, 2021

Liao, Y. H., Su, Y. L., & Chen, Y. C. “The Influence of Neem Oil and Its Glyceride on the Structure and Characterization of Castor Oil-Based Polyurethane Foam. Polymers”. Vol 13(12) Pp.103-106,2020.

Bhan, U., Singh, D., & Ranganathan, A. “Effect of different loads on the friction and wear characteristics of material lubricated with neem oil”. Materials Today: Proceedings vol. 46 pp. 10113-10116, 2021

Ghosh, P., Hoque, M., Roy, D. “Castor oil and acrylate-based copolymer as a green additive for lubricating oil”. Polymer pp. 734-737, 2020

Quinchia, L. A., Delgado, M. A., Valencia, C., Franco, J. M., & Gallegos, C. “Natural and synthetic antioxidant additives for improving the performance of new biolubricant formulations”. Journal of agricultural and food chemistry, 59(24) pp. 12917-12924, 2011

Nandiyanto, A. B. D., Oktiani, R., & Ragadhita, R. “How to read and interpret FTIR spectroscope of organic material”. Indonesian Journal of Science and Technology, 4(1) pp. 97-118, 2019

Mohammed, A. H., Mahmood, T. A., Yousif, S. A., & Musa, A. “Sunflower and Linseed Oils with Decyl Methacrylate Based Copolymers as Green Lubricating Additives”. In Materials Science Forum (Vol. 1045), pp. 109–116, 2021.

Downloads

Published

2024-12-31

How to Cite

Sanusi, F., Musa, A., & Bello, A. (2024). Preparation of Neem Oil and Acrylonitrile Based Copolymeric Materials as a Potential Bio-Based Additives and Its Effect on Pour Point Depressant of a Lube Oil. International Journal of Scientific Research in Chemical Sciences, 11(6), 8–12. Retrieved from https://ijsrcs.isroset.org/index.php/j/article/view/180

Issue

Section

Research Article

Similar Articles

1 2 3 4 5 6 > >> 

You may also start an advanced similarity search for this article.