Environmental Benefits of Using a Low-Cost Adsorbent for the Removal of Nickel Metal Ions from Portable Water
Keywords:
Adsorbent, nickel metal ions, adsorption, isotherm, kinetics, thermodynamicsAbstract
The study investigates the use of Matki seed husk (MtSH), a low-cost and abundant agricultural waste, as adsorbent for removing nickel metal ions from aqueous solutions. In this research, the effect of contact time, effect of temperature, effect of adsorption dose, pH and initial concentration of metal ions on MtSH adsorbent capacities has been investigated. The adsorption of Ni2+ metal ions was investigated by using pseudo-first and pseudo-second order kinetic models. The adsorption kinetics was well described by the pseudo-second-order kinetic model, and equilibrium data were successfully fitted to the Freundlich models. The optimum adsorption was observed at pH 5, with spontaneous and exothermic adsorption. The study recommends MtSH as a cost-effective and easily available bio-adsorbent for removing toxic heavy Ni2+ metal ions from industrial wastewater. The bio-adsorbent can be reused up to five times without significant loss of adsorption capacity. Overall, this present study demonstrates that Matki seed husk can be a promising low-cost bio-adsorbent for the removal of Ni2+ metal ions from aqueous solution, offering significant environmental benefits. The results of this study can be used to develop cost-effective and sustainable strategies for wastewater treatment and pollution control.
References
World Health Organization Guidelines for drinking-water quality fourth edition, 2022.
United States Environmental Protection Agency. Hazardous waste: Nickel, 2019.
Sadia Zafar, Dilara A. Bukhari, Abdul Rehman, Azo dyesdegradation by microorganisms – An efficient and sustainable approach, Saudi Journal of BiologicalSciences, Vol.29, Issue.12, pp.1-9, 2022. https://doi.org/10.1016/j.sjbs.2022.103437
Muhammad Zobayer Bin Mukhlish, Shekh Nazibunnesa, Shariful Islam, Abu Saleh Al Mahmood , Md Tamez Uddin, Preparation of chemically and thermally modified water caltrop epicarp (Trapa natans L.) adsorbent for enhanced adsorption of Ni (II) from aqueous solution, Heliyon. Vol.9, Issue.11, 2023. https://doi.org/10.1016/j.heliyon.2023.e21862.
P. K. Baskaran, B. R. Venkatraman, M. Hema and S. Arivoli, Adsorption studies of copper ion by low cost activated carbon. J. Chem. Pharm Res. Vol. 2, Issue 5, pp. 642-635, 2010.
C. B. Chandran, D. Singh, P. Nigam, Remediation of textile effluent using agricultural residues. Appl. Biochem. Biotechnol, Vol. 102, pp. 207-212, 2002.
Emad N. El Qada, Emad A. Abdelghany, Yehia H. Magdy., Utilization of activated carbon for the removal of basic dyes in fixed-bed International Journal ofEnergy and Environment, vol, 4, Issue 5, pp. 815-824, 2013.
Enrique Torres. Biosorption: A Review of the Latest Advances, Processes, Vol.8, Issue.12, pp.1-23, 2020. https://doi.org/10.3390/pr8121584.
A. Saeed, M. Sharif, M. Iqbal, Application potential of grapefruit peel as dye sorbent: kinetics, equilibrium and mechanism of crystal violet adsorption. Journal Hazardous Materials, Vol.179, Issue 1-3, pp.564–572, 2010. https://doi.org/10.1016/j.jhazmat.2010.03.041.
Puspa Lal Homagai, Rachana Poudel, Sujan Poudel, Ajaya Bhattarai, Adsorption and removal of crystal violet dye from aqueous solution by modified rice husk. Heliyon, Vol.8, Issue 4, pp.1-9, 2022. https://doi.org/10.1016/j.heliyon.2022.e09261.
Arunachalam Thirunavukkarasu, Rajarathinam Nithya,Raja Sivashankar, Continuous fixed-bed biosorption Process: A review, Chemical Engineering Journal Advances; vol. 8, pp. 1-23, 2021. https://doi.org/10.1016/j.ceja.2021.100188.
Razia Sulthana, Syed Noeman Taqui, Akheel Ahmed Syed, Adsorption of Crystal Violet Dye from Aqueous Solution using Industrial Pepper Seed Spent: Equilibrium, Thermodynamic, and Kinetic Studies, Adsorption Science & Technology, Vol. 6, pp. 1-20 https://doi.org/10.1155/2022/9009214.
D. B. Jirekar, Ghumare Pramila, Comparative Study of Adsorption of Red Gram Seed Husk for the Adsorption of Congo Red, Crystal Violet, and Methylene Bluefrom Aqueous Solution, Journal of Science and Technology, Vol. 07, Issue 3, pp.35-41, 2022. https://doi.org/10.46243/jst.2022.v7.i03.pp35-41
Bulus Habila, Ukoha Pius O., Ezeh Emmanuel C., Oguejiofo Ujam T., Attah John C., Simon Moses S, Synthesis and Characterization of Immobilized Thiolactic Ligand System for the Detoxification of Tannery Wastewater, European Journal of Applied Sciences, Vol.8, Issue 5, 18-27, 2020. https://doi.org/10.14738/aivp.85.8790
S. J. Patil, A. G. Bhole and G. S. Natrajan, Scavenging of Ni (II) metal ions by adsorption on PAC and babhul bark, Jour. of Envioron. Sci. and Eng., vol. 48, Issue 3, pp..203-208, 2006.
Halil Hasar, “Adsorption of nickel (II) from aqueous solution onto activated carbon prepared from almond husk”, J. Haz. Mat., vol. 97, Issue 1-3, pp. 49-57, 2003. https://doi.org/10.1016/S0304-3894(02)00237-6.
E Demirba?, M Kobya, S Oncel, S Sencan., Removal of Ni (II) from aqueous solution by adsorption onto hazelnut shell activated caebon : equilibrium studies, Bioresource Technol., vol. 84, Issue 3, pp.291-293, 2002. https://doi.org/10.1016/s0960-8524(02)00052-4.
Mao Yanli, Hu Hongwei, Yan Yongsheng and Ou Hongxiang, A novel extracellular biopolymer produced from Pseudomonas fluorescens C-2: preparation, characterisation and adsorption behaviours towards nickel (II) ions in aqueous solution, International Journal of Materials and Structural Integrity, Vol. 6, Issue 1, pp.74-93, 2012. https://doi.org/10.1504/IJMSI.2012.046189.
Lisbania Velarde, Mohammad Sadegh Nabavi, Edwin Escalera, Marta-Lena Antti, Farid Akhtar. Adsorption of heavy metals on natural zeolites: A review,Chemosphere, vol. 328, pp. 1-16, 2023. https://doi.org/10.1016/j.chemosphere.2023.138508.
Aiyesanmi, Ademola Festus Adebayo, Matthew Ayorinde, Okoronkwo, Afamefuna Elvis, Ekujumi, Oluwafemi, Adsorption of Nickel (II) from Aqueous Solution Using Leucaena leucocephala Shells, Iran. J. Chem. Chem. Eng, Vol.41, Issue.8, pp.2755-2770, 2022.
Pranali Choudhari, Sarang S. Dhote, Mamata R. Lanjewar, Enhanced Nickel Removal from Aqueous Solutions using Chemically Modified Tabeubea Rosea Leaves Powder as Biosorbent. Mapana - Journal of Sciences, Vol.23, Issue.1, pp.93-117, 2024. https://doi.org/10.12723/mjs.68.5.
S. A. Yahya, M. I. El-Barghouthi, A. H. El-Sheikh and G. M. Walker, “Effect of Solution pH, Ionic strength and temperature on adsorption behavior of rective dyes on activated Carbon”, Dyes and Pigment, Vol.77, pp.16-23, 2008.
Liu et al. Adsorption removal of nickel (II) ions from aqueous solution using modified peanut shell: A study using response surface methodology. Journal of Environmental Management, vol. 238, Issue 5, pp. 111-121, 2019.
D. B. Jirekara, Mazahar Farooqui; Adsorption of Congo Red Dye from Aqueous solution using Eco- Friendly low cost material prepared from Cicer arientinum, Arab J. Phys. Chem., Vol.2, Issue.1, pp.1-6, 2015.
Mazhar Farooqui, Sayyad Sultan, Maqdoom Farooqui, and S. H. Quadri, Adsorption studies of heavy metal ion by low cost agricultural by-products - Bajara Powder, Ind. J. of Chem. Techol. Vol.11, Issue.2, pp.190-193, 2004.
O. Hamdaoui, “Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick,” Journal of hazardous materials, Vol.135, Issue.1–3, pp.264–273, 2006, https://doi.org/10.1016/j.jhazmat.2005.11.062
E. Voudrias, K. Fytianos, and E. Bozani, “Sorption–desorption isotherms of dyes from aqueous solutions and wastewaters with different sorbent materials,” Global Nest Int. J, Vol.4, Issue.1, pp.75–83, 2002, Accessed:Sep.17,2024.
S. Mohan and J. Karthickeyan "Removal of lighin and tannin colour from aqueous solution by adsorption on to activated carbon solution by adsorption on to activated charcoal, Environ. pollut., Vol.97,1Issue.1-2, pp.83-187, 1997.
N. Kannan, and P. Sarojini. “Studies on the removal of manganese (II) ions by adsorption on commercial activated carbon” Ind. Env. Prot. Vol.30, Issue.5, pp.404-408, 2010.
Hinda Lachheb, Eric Puzenat, Ammar Houas, Mohamed Ksibi, Elimame Elaioui, Chantal Guillard and Jean-Marie Herrmann; Photocatalytic degradation of various types of dyes (alizarin S, crocein orange G, methyl red, congo red, methyl biue) in water by UV- irradiated titania, Appl. Catalysis B:Env., Vol.39, pp.75-90, 2002. DOI: 10.1016/s0269-7491(97)00025-0
Vipasiri Vimonses, Shaomin Lei, Bo Jin, Chris W. K. Chow and Chris Saint; Adsorption of congo red by three Australian kaolins, Appl. Clay Sci., Vol.43, Issue.3-4, pp.465-472, 2009. https://doi.org/10.1016/j.clay.2008.11.008
Rais Ahmad and Rajeev kumar; Adsorptive removal of congo red dye from aqueous solution using bael shell carbon, Apll. Surf. Sci. Vol.257, Issue.5, pp.1628-1633, 2010. https://doi.org/10.1016/j.apsusc.2010.08.111
J. R. Kulkarni and V. S. Shrivastava; Removal of congo red (dye) by using chemically modified sawdust, Asian J. Chem. Vol.16, Issue.2, pp.795-799, 2004
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors contributing to this journal agree to publish their articles under the Creative Commons Attribution 4.0 International License, allowing third parties to share their work (copy, distribute, transmit) and to adapt it, under the condition that the authors are given credit and that in the event of reuse or distribution, the terms of this license are made clear.
